Synthesis and X-ray Structure of the First Cluster-Stabilized Phosphaallene, 3-η2-t-BuP(C=CH(C6H5))>FeCo2(CO)9

DOI: 10.1021/ja00285a021

Source and publish data:

Journal of the American Chemical Society p. 8007 - 8010 (1986)

Update date:2022-07-30

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Authors:

Mathieu, Rene

Caminade, Anne-Marie

Majoral, Jean-Pierre

Daran, Jean-Claude

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Article abstract of DOI:10.1021/ja00285a021

The complex <μ₃-η²-t-Bu(C=CH(C6H5))>FeCo2(CO)6 (6) has been obtained in3 percent yield by the following sequence of reactions: (i) synthesizing Fe(CO)4 (1) by the reaction of ^- with P(t-Bu)(CCPh)C

Full text of DOI:10.1021/ja00285a021

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