Chemistry of β-Triketones. 1. Structure of Schiff Base Intermediates of 2-Acyl-1,3-indandiones

DOI: 10.1021/jo00171a034

Source and publish data:

Journal of Organic Chemistry p. 4326 - 4329 (1983)

Update date:2022-08-02

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Authors:

Sawhney, Kailash N.

Lemke, Thomas L.

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Article abstract of DOI:10.1021/jo00171a034

Schiff base formation has been shown to occur preferentially at the exocyclic carbonyl of 2-acyl-1,3-indandiones (1).The resulting addition product exists either as an open-chain compound (10-16) or as a cyclic hemiketal (19-27).The size of the acyl subst

Full text of DOI:10.1021/jo00171a034

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