Bulletin of the Chemical Society of Japan p. 1420 - 1423 (1983)
Update date:2022-08-05
Topics:
Tada
Inoue
Okabe
The photolysis of 2-aryl-2-ethoxy-2-phenylethyl cobaloxime followed by hydrolysis gave two kinds of substituted 1,2-diphenylethanones arising via phenyl or substituted-phenyl migration. The substituent effect on the aryl rearrangement is similar to that on the reported neophyl rearrangement, and the rearrangement takes place by a radical mechanism without the deep involvement of cobaloxine(II).
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