Journal of Organic Chemistry p. 4236 - 4240 (1983)
Update date:2022-08-03
Topics:
Cacchi, S.
Arcadi, A.
Aryl iodides have been found to react with α,β-unsaturated ketones in the presence of catalytic amounts of palladium, an excess of formic acid, and triethylamine, giving rise to conjugate addition type products.The electron-withdrawing power of the group attached to the olefinic double bond, the substituent β to the carbonyl group, and the basic reaction medium appear to effect greatly the conjugate addition/vinylic substitution ratio.
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