1-LITHIO-1-BENZENESULFINYL-2-TRIMETHYLSILYLETHANE AS A 2-TRIMETHYLSILYLVINYL ANION EQUIVALENT IN REACTIONS WITH ALHEDYDES, KETONES AND EPOXIDES

DOI: 10.1016/S0040-4039(00)81928-0

Source and publish data:

Tetrahedron Letters p. 2371 - 2374 (1983)

Update date:2022-08-03

Topics:

Authors:

Hsiao, C-N.

Shechter, H.

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Article abstract of DOI:10.1016/S0040-4039(00)81928-0

Aldehydes, ketones and epoxides give adducts with 1-lithio-1-benzenesulfinyl-2-trimethylsilylethane which upon neutralization eliminate benezenesulfenic acid efficiently at 76 deg C to yield trans-3-(trimethylsilyl)allyl alcohols and trans-4-(trimethylsilyl)-3-alken-1-ols.

Full text of DOI:10.1016/S0040-4039(00)81928-0

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