1-LITHIO-1-BENZENESULFINYL-2-TRIMETHYLSILYLETHANE AS A 2-TRIMETHYLSILYLVINYL ANION EQUIVALENT IN REACTIONS WITH ALHEDYDES, KETONES AND EPOXIDES

DOI: 10.1016/S0040-4039(00)81928-0

Source and publish data:

Tetrahedron Letters p. 2371 - 2374 (1983)

Update date:2022-08-03

Topics:

Authors:

Hsiao, C-N.

Shechter, H.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)81928-0

Aldehydes, ketones and epoxides give adducts with 1-lithio-1-benzenesulfinyl-2-trimethylsilylethane which upon neutralization eliminate benezenesulfenic acid efficiently at 76 deg C to yield trans-3-(trimethylsilyl)allyl alcohols and trans-4-(trimethylsilyl)-3-alken-1-ols.

Full text of DOI:10.1016/S0040-4039(00)81928-0

Products guided by the article

Product name:(E)-1,1-Diphenyl-3-trimethylsilanyl-prop-2-en-1-ol

Cas No:87428-73-7

R&D Labs maybe for 87428-73-7

Du-Hope International Group

website:http://www.np-chem.com

Contact:0086-25-52346877

Address:199, Jian Ye Road, Nanjing, China
Xi'an Herbland Tech Inc.

Contact:+86-29-88710656

Address:South Tai bai Road, High Tech Development Zone, Xi'an China
Nanjing Raise Pharmatech Co., Ltd

website:http://www.raisechem.com

Contact:+86-25-58649566

Address:B381,No.606,Ningliu Road,Jiangbei New Area,Nanjing,Jiangsu Province,China
Zhejiang Chemicals Import & Export Corporation

Contact:86-571-87043088

Address:No.37,Qingchun Road,Hangzhou,China
Xi'an Tizan Tech & Industry Co., Ltd.

Contact:86-18629066522

Address:C3009 TANG FENG INTERNATIONAL PLAZA, NO.18 FENGHUI NAN ROAD, XI'AN HIGH TECH ZONE, 710075 CHINA.

Relevant to this article

Kinetic resolution of oxazinones: An organocatalytic approach to enantiomerically pure β-amino acids

Doi:10.1002/anie.200502003
(2005)
On the regioselectivity of palladium catalyzed cross-coupling reactions of alkenylsilanes: participation of β-cationic organosilicate-palladium species during the transmetallation

Doi:10.1016/0022-328X(94)87042-X
(1994)
Simple total syntheses of biologically active pentathiadecane natural products, 2,4,5,7,9-pentathiadecane 2,2,9,9-tetraoxide (dysoxysulfone), from Dysoxylum richii, and 2,3,5,7,9-pentathiadecane 9,9-dioxide, the misidentified lenthionine precursor SE-3 fr

Doi:10.1021/jo00088a001
(1994)
Kinetic Analysis of the Rearrangement of a Conformationally Constrained α-Cyclopropylbenzyl Radical

Doi:10.1021/jo00092a003
(1994)
Asymmetric allylation/pauson-khand reaction: A simple entry to polycyclic amines. Application to the synthesis of aminosteroid analogues

Doi:10.1021/ol500142c
(2014)
Studies towards the synthesis of alkyl N-(4-nitrophenyl)-3/2-oxomorpholine- 2/3-carboxylates

Doi:10.1002/hlca.201300085
(2013)

Article Doi