Journal of Organometallic Chemistry p. 305 - 316 (1983)
Update date:2022-07-31
Topics:
Bitterwolf, Thomas E.
Biphenylbis(chromium dicarbonyl)-μ-bis(diphenylphosphido)methane and its arsenic analog have been prepared in good yield by UV irradiation of biphenylbis(chromium tricarbonyl) and bis(diphenylphosphido)methane or bis(diphenylarsino)methane in benzene.Addition of strong acid to these dinuclear compounds results in rapid dihydrogen evolution and subsequent decomposition of the oxidized chromium species.A scheme for the dihydrogen elimination reaction is proposed in which both metal centers are protonated in an oxidative addition step, followed by reductive elimination of dihydrogen from the two metal centers.
Chengdu ZY Biochemical Technology Co., LTD
Contact:0086-28-88680086
Address:170 Qingpu Road, Shouan Town, Pujiang County
Baicao Pharmaceutical Co., Ltd.
website:http://www.jxbaicao.com
Contact:+86-796-8113329
Address:It (country) economic and technological development zone of the jinggang mountains
Shanghai better-in Medical Technology Co.,LTD.
Contact:+86-21-38921049
Address:Lane 720 zhangjianggaoke cailun road, Pudong, Shanghai, room 513
Contact:+86-22-83718541
Address:32th Floor, Rongqiao Center Intersection of Changjiang Road and Nankai Six Road Nankai District Tianjin 300102, China
website:http://www.easchem.com
Contact:+86-731-89722861 89722891
Address:2/F-4/Bld Colorful Palace, No.605 Changsha Ave, Yuhua Area Changsha Hunan China.
Doi:10.1248/cpb.31.1518
(1983)Doi:10.1002/zaac.201500579
(2015)Doi:10.3184/174751911X13230815130502
(2011)Doi:10.1248/cpb.31.1659
(1983)Doi:10.1021/jo00175a038
(1984)Doi:10.1021/jo00176a005
(1984)
