Total Synthesis of Racemic Silphinene

DOI: 10.1021/jo00142a037

Source and publish data:

Journal of Organic Chemistry p. 4173 - 4174 (1982)

Update date:2022-08-02

Topics:

Authors:

Leone-Bay, Andrea

Paquette, Leo A.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00142a037

The tricyclic sesquiterpene silphinene (1) has been synthesized in full stereocontrolled fashion from 4,4-dimethylcyclopentenone by o twofold five-ring annulation sequence in 15 steps and 10percent overall yield.

Full text of DOI:10.1021/jo00142a037

Products guided by the article

Product name:Thiocarbonic acid O-p-tolyl ester O-((3aR,5aR,8aR)-3a,5,5-trimethyl-8-oxo-decahydro-cyclopenta[c]pentalen-1-yl) ester

Cas No:87802-45-7

R&D Labs maybe for 87802-45-7

Chengdu Cogon Bio-tech Co., Ltd.

Contact:86-28-85171192

Address:NO.52.YongFeng Rd. Chengdu,610041,P.R.China.
Lianyungang Ningkang Chemical Co., Ltd

Contact:.+86-518-88588008

Address:http://www.chemnk.com
Changzhou Kingyo Chemical Corporation Ltd.

website:http://www.kingyochem.com

Contact:+86-519-85105717

Address:19# Wuqing North Road, Changzhou , Jiangsu, China
Xiamen Kaijia Imp & Exp Co., Ltd.

Contact:86-592-5101177

Address:Room406 Luhui Building No. 65 Haitian Road Huli Xiamen,China.
Taixing Joxin Bio-tec Co.,Ltd.

website:http://www.joxbio.com

Contact:86-523-87558858 87612088

Address:No.88, chengdong industrial park

Relevant to this article

Doi:10.1021/ja01519a070
(1959)
Substituted benzeneseleninic acids as bidentate ligands. Synthesis and spectroscopic studies of manganese(II) and iron(II) complexes

Doi:10.1016/0584-8539(83)80039-7
(1983)
The chemical synthesis of bioactive glycosylphosphatidylinositols from Trypanosoma cruzi containing an unsaturated fatty acid in the lipid

Doi:10.1002/anie.200502779
(2006)
Regioselective para-Carboxylation of Catechols with a Prenylated Flavin Dependent Decarboxylase

Doi:10.1002/anie.201708091
(2017)
Guanidine hydrochloride catalyzed efficient one-pot pseudo five-component synthesis of 4,4′-(arylmethylene)bis(1H-pyrazol-5-ols) in water

Doi:10.1080/00397911.2019.1643483
(2019)
An efficient synthesis of carbazole-based secretory phospholipase A ₂ (sPLA₂) inhibitors LSN433771 and LSN426891

Doi:10.1016/j.tetlet.2005.12.043
(2006)

Article Doi