Total Synthesis of Racemic Silphinene

DOI: 10.1021/jo00142a037

Source and publish data:

Journal of Organic Chemistry p. 4173 - 4174 (1982)

Update date:2022-08-02

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Authors:

Leone-Bay, Andrea

Paquette, Leo A.

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Article abstract of DOI:10.1021/jo00142a037

The tricyclic sesquiterpene silphinene (1) has been synthesized in full stereocontrolled fashion from 4,4-dimethylcyclopentenone by o twofold five-ring annulation sequence in 15 steps and 10percent overall yield.

Full text of DOI:10.1021/jo00142a037

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Product name:Thiocarbonic acid O-p-tolyl ester O-((3aR,5aR,8aR)-3a,5,5-trimethyl-8-oxo-decahydro-cyclopenta[c]pentalen-1-yl) ester

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