SYNTHESIS OF SYN-7-BENZYLOXY-4-METHYLBICYCLOHEPT-5-EN-2-ONE, AN INTERMEDIATE FOR THE SYNTHESIS OF STEROIDS AND TRICOTHECANES; TANDEM ANIONIC - SIGMATROPIC REARRANGEMENT

DOI: 10.1016/S0040-4039(00)88061-2

Source and publish data:

Tetrahedron Letters p. 2931 - 2934 (1983)

Update date:2022-08-03

Topics:

Authors:

Jung, Michael E.

Hatfield, Gregory L.

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Article abstract of DOI:10.1016/S0040-4039(00)88061-2

The enone ether 1 has been prepared from 2-methylcyclopentenone and converted into the hydrindenone 2; the first example of a tandem anionic <1,3>-<3,3> sigmatropic rearrangement is reported.

Full text of DOI:10.1016/S0040-4039(00)88061-2

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