SYNTHESIS OF SYN-7-BENZYLOXY-4-METHYLBICYCLOHEPT-5-EN-2-ONE, AN INTERMEDIATE FOR THE SYNTHESIS OF STEROIDS AND TRICOTHECANES; TANDEM ANIONIC - SIGMATROPIC REARRANGEMENT

DOI: 10.1016/S0040-4039(00)88061-2

Source and publish data:

Tetrahedron Letters p. 2931 - 2934 (1983)

Update date:2022-08-03

Topics:

Authors:

Jung, Michael E.

Hatfield, Gregory L.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)88061-2

The enone ether 1 has been prepared from 2-methylcyclopentenone and converted into the hydrindenone 2; the first example of a tandem anionic <1,3>-<3,3> sigmatropic rearrangement is reported.

Full text of DOI:10.1016/S0040-4039(00)88061-2

Products guided by the article

Product name:3-Benzoyloxyquadricyclane

Cas No:87848-36-0

R&D Labs maybe for 87848-36-0

Hebei Fulong Import & Export Co., Ltd.

Contact:86-311-87795661

Address:15A19 Zhongyuan Building,368 Youyi North Street,Shijiazhuang 050070,China
Qingzhou Baibang import and export co.,Ltd

Contact:+86-536-3265899

Address:No.338, Tuoshan Road
SuZhou Bichal Biological Technology CO.,LTD

Contact:+86-512-68051130

Address:NO.32 huoju road HI-TECH Industrial development zone SuZhou China
Daqing E-shine Chemical Co.,LTD

Contact:0086-024-31285112

Address:Hongweiyuan area, Ranghulu district
Jinan Yijialian Economic and Trade Development Co., Ltd.

Contact:+86 0531-66729596

Address:jinan

Relevant to this article

One step synthesis of 1,5-diaryl pyridin-2(1H)-ones from 2-aryl vinamidinium salts and N-aryl cyanoacetamides

Doi:10.1016/j.tet.2014.09.041
(2014)
Doi:10.1039/C29700000913
(1970)
Doi:10.1016/S0040-4039(01)86237-7
(1979)
Investigation of transition metal-imido bonding in M(NBu^t) ₂(dpma)

Doi:10.1021/ic049644o
(2004)
Regioselective and enantiospecific rhodium-catalyzed allylic alkylation reactions using copper(I) enolates: Synthesis of (-)-sugiresinol dimethyl ether

Doi:10.1021/ja035983p
(2003)
Doi:10.1002/hlca.19790620524
(1979)

Article Doi