Formation of η6-Pyridine Complexes of Molybdenum(0) by a ? to ? Rearrangement in Mo(N2)2(NC5H4-4-R)(PMePh2)3, R = H, Me

DOI: 10.1039/c39830000909

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 909 - 910 (1983)

Update date:2022-08-05

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Authors:

Morris, Robert H.

Ressner, Joel M.

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Article abstract of DOI:10.1039/c39830000909

The new complexes trans,mer-Mo(N2)2(NC5H4-4-R)(PMePh2)3, R = H, Me lose dinitrogen in vacuo at 25 deg C in arene solvents to give Mo(η⁶-NC5H4R)(PMePh2)3, the first stable η⁶-pyridine complexes of molybdenum.

Full text of DOI:10.1039/c39830000909

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