Mediation of the Reactivity of the Strong Lewis Acid TiCl4 by Complexation with XPh3

DOI: 10.1021/jo00070a004

Source and publish data:

Journal of Organic Chemistry p. 4783 - 4784 (1993)

Update date:2022-08-05

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Authors:

Suzuki, Ichiro

Yamamoto, Yoshinori

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Article abstract of DOI:10.1021/jo00070a004

Lewis acid-base combinations TiCl4*XPh3 (X = As,Sb,Bi) have been developed to mediate the Lewis acidity of TiCl4.The inverse addition of TiCl4*AsPh3 to 2-(benzyloxy)propanal (1) and allylstannane 2 provided a chelation-controlled product 3 with high diast

Full text of DOI:10.1021/jo00070a004

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