The Reaction of Arenediazonium Ions with Cycloheptatriene (cht) and with 4-cht)>: Azo-coupling versus Hydrazone Formation

DOI: 10.1039/DT9830001465

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 1465 - 1468 (1983)

Update date:2022-08-03

Topics:

Authors:

Connelly, Neil G.

Lucy, Andrew R.

Sheridan, John B.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/DT9830001465

The complex 4-cht)> (cht= cycloheptatriene) and give 5-C7H8N2C6H4NO2-p>> (1) which is deprotonated on alumina to give syn- and anti-isomers of the hydrazone complex 4-C7H6NN(H)C6H4NO2-p>> (2); the C7H6NN(H)C6H4NO2-p is detached from the metal on reaction with N(O)Me3*2H2O.By contrast, free cycloheptatriene and in water yield 4-hydroxy-5-p-nitrophenylazobicyclo<4.1.0>hept-2-ene.

Full text of DOI:10.1039/DT9830001465

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:[Fe(CO)3(η5-C7H8N2C6H4NO2-p)][BF4]

Cas No:87969-31-1

R&D Labs maybe for 87969-31-1

Shijiazhuang Frontierchem Co., Ltd.

Contact:+86-311-89271196

Address:4-4-202 No.15 Biandian Street,Shijiazhuang
Hangzhou Haiqiang Chemical Co.,Ltd.

Contact:+86-571-86960370

Address:Add: 5/F, Around Town North Road,No. 10, Hangzhou, Zhejiang,China
Hybio Pharmaceutica Co.,Ltd

Contact:+86 755 26588093

Address:No.9 Linkong West Street, Hengdian Street, Huangpi District, Wuhan City, China.
Hunan Shineway Enterprise Co., Ltd.

Contact:+86-731-86303875

Address:118, Huanghua International Airport Road, Huanghua Town, Changsha, Hunan 410137, China
Arshine Pharmaceutical Co., Limited

website:http://www.cnarshine.com

Contact:0731-88503671

Address:Room 1109.Block C3, Lugu Enterprise Plaza,No.27 Wenxuan Road,Changsha National Hi-Tech Industrial Development Zone,Hunan ,P.R.China

Relevant to this article

Synthesis, oxidation and dehydrogenation of cyclic N,O- and N,S-acetals. Part 1. Transformation of N,S-acetals: 3-acyl-1,3,4-thiadiazolines

Doi:10.3987/COM-04-10137
(2004)
Total syntheses of (-)-grandinolide and (-)-sapranthin by the sharpless asymmetric dihydroxylation of methyl trans-3-pentenoate: Elucidation of the stereostructure of (-)-sapranthin

Doi:10.1002/(SICI)1521-3765(19981102)4:11<2342::AID-CHEM2342>3.0.CO;2-Q
(1998)
Doi:10.1039/jr9530000119
(1953)
Living Ziegler-Natta polymerization by early transition metals: Synthesis and evaluation of cationic zirconium alkyl complexes bearing β-hydrogens as models for propagating centers

Doi:10.1021/ja057866v
(2006)
An in-based 3D metal-organic framework as heterogeneous Lewis acid catalyst for multi-component Strecker reactions

Doi:10.1016/j.ica.2018.04.037
(2018)
Direct on-resin synthesis of peptide-^αthiophenylesters for use in native chemical ligation

Doi:10.1021/ol052811j
(2006)

Article Doi