THE OXIDATIVE CLEAVAGE OF BY STRONG ACIDS IN ACETONITRILE SOLUTION

DOI: 10.1016/S0022-328X(00)99843-7

Source and publish data:

Journal of Organometallic Chemistry p. C81 - C82 (1983)

Update date:2022-07-29

Topics:

Authors:

Callan, Brian

Manning, A.R.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0022-328X(00)99843-7

In acetonitrile solution and the absence of O2, strong acids HX cleave instantaneously to X, Fe(η-C5H5)(CO)2X> or a mixture of the two.The reaction does not take place in solvents such as dichloromethane, tetrahydrofuran or methanol, or with weaker acids having pK_a (in water) > ca. 1.

Full text of DOI:10.1016/S0022-328X(00)99843-7

Products guided by the article

Product name:(C₅H₅)Ru(CO)2(NCCH₃)⁽¹⁺⁾*CH₃C₆H₄SO₃^(1-)=((C₅H₅)Ru(CO)2(NCCH₃))OSO₂C₆H₄CH₃

Cas No:87973-47-5

R&D Labs maybe for 87973-47-5

Quhua Zhongxing Refrigeration Technology Co.,Ltd.

Contact:+86-5708886618

Address:318 Bulding 2, No.866 Quhua Rd.,Kecheng District
Binzhou Holly Pharmaceutical Co.,Ltd.

Contact:74517

Address:No.15 Dapu Road,Huangpu District Shanghai,P.R.China
Shandong Chi Run Chemical Trading Co., Ltd.

Contact:+86 15953830388 +86 18254817951

Address:NO.61 Fushan Road, Xintai Economic Development Zone, Shandong Province
Anhui Jiatiansen Agrochemical Co.,Ltd

Contact:15366811918

Address:chemical industrial park,xiangyu town,dongzhi county,anhui,china
ZCIC INTERNATIONAL LTD

Contact:+86-512-56795332

Address:No227 Shuanglong Rd, Fenghuang, Zhangjiagang

Relevant to this article

Dechalcogenative allylic selenosulfide and disulfide rearrangements: Complementary methods for the formation of allylic sulfides in the absence of electrophiles. Scope, limitations, and application to the functionalization of unprotected peptides in aqueous media

Doi:10.1021/ja072969u
(2007)
Diatomic phenols as nucleophilic components in the carbonylation of the chelated C,N-palladacycle of the ferrocene series

Doi:10.1007/s11172-005-0206-7
(2004)
Kinetics of Zr-Catalyzed Cycloalumination of Alkenes and Alkynes in the Dzhemilev Reaction

Doi:10.1134/S0023158420010085
(2020)
The influence of phenyl and phenoxy modification in the hydrophobic tails of di-n-alkyl phosphate amphiphiles on aggregate morphology

Doi:10.1039/b514285g
(2006)
Catalytic asymmetric desymmetrization of meso-diamide derivatives through enantioselective N-allylation with a chiral π-allyl Pd catalyst: Improvement and reversal of the enantioselectivity

Doi:10.1021/jo052488y
(2006)
Development of Bifunctional Thiourea Organocatalysts Derived from a Chloramphenicol Base Scaffold and their Use in the Enantioselective Alcoholysis of meso Cyclic Anhydrides

Doi:10.1002/cctc.201600228
(2016)

Article Doi