THE OXIDATIVE CLEAVAGE OF BY STRONG ACIDS IN ACETONITRILE SOLUTION

DOI: 10.1016/S0022-328X(00)99843-7

Source and publish data:

Journal of Organometallic Chemistry p. C81 - C82 (1983)

Update date:2022-07-29

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Authors:

Callan, Brian

Manning, A.R.

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Article abstract of DOI:10.1016/S0022-328X(00)99843-7

In acetonitrile solution and the absence of O2, strong acids HX cleave instantaneously to X, Fe(η-C5H5)(CO)2X> or a mixture of the two.The reaction does not take place in solvents such as dichloromethane, tetrahydrofuran or methanol, or with weaker acids having pK_a (in water) > ca. 1.

Full text of DOI:10.1016/S0022-328X(00)99843-7

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Product name:(C₅H₅)Ru(CO)2(NCCH₃)⁽¹⁺⁾*CH₃C₆H₄SO₃^(1-)=((C₅H₅)Ru(CO)2(NCCH₃))OSO₂C₆H₄CH₃

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