Stable Simple Enols. 10. 500-MHz 1H NMR of Trimesitylethenol and Deuterated Analogues: Complete Signal Assignments and Direct Determination of Equilibrium Steric Isotope Effects from the NMR Integrals of the Isotopomeric Enols

DOI: 10.1021/ja00305a021

Source and publish data:

Journal of the American Chemical Society p. 5450 - 5459 (1985)

Update date:2022-08-05

Topics:

Authors:

Biali, Silvio E.

Rappoport, Zvi

Hull, William E.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/ja00305a021

E/Z mixtures of the isotopomers Mes*C(Mes)=C(OH)Mes (7a/7b) and Mes*C(Mes)=C(OH)Mes* (8a/8b) were prepared by addition of MesMgBr and Mes*Br to Mes*C(Mes)=C=O.High resolution 1H NMR at 500 MHz of trimesityleth

Full text of DOI:10.1021/ja00305a021

Products guided by the article

Product name:(Z)-1-mesityl-2-phenyl-2-(2,4,6-tridenteriomethylphenyl) ethenol

Cas No:88180-90-9

R&D Labs maybe for 88180-90-9

Jiangxi Lanqi Fine Chemical S&T Co., Ltd.

Contact:+86-21-64891143

Address:XinJiShan Industrial Area, Zhangshu City, JiangXi Province, China
JIANGSU GRAND XINYI PHARMACEUTICAL CO.,LTD

website:http://www.xypharm.com/

Contact:+86-515-84383317

Address:Chenli Road,Costal Chemical Area Binhai,Yancheng, Jiangsu,China
Dongtai Xinyuan Chemical Co., Ltd.

Contact:+86-21-56733000

Address:404F, 99Nong No.117 Zhongtan Rd. Shanghai
QINGDAO HONG JIN CHEMICAL CO.,LTD.

website:http://www.hongjinchem.com

Contact:+86-532-83657313

Address:2ND Building, 8 Shangqing Road, Qingdao, Shandong Province, China.
Wuhan Hanye Chemical New Material Co.,Ltd

Contact:+86-27-85308141

Address:LiuDian, Panlongcheng Economic Development Zone, HuangPi district, Wuhan, Hubei 430311 P.R.China

Relevant to this article

Pd(II)-catalyzed enantioselective oxidative tandem cyclization reactions. Synthesis of indolines through C-N and C-C bond formation

Doi:10.1021/ja060291x
(2006)
SYNTHESIS AND EXTRACTION PROPERTIES OF 3-(1'-HYDROXYETHYL)-2,6-ALKANEDIOLS

Doi:10.1007/BF00954663
(1983)
Barriers to internal rotation around the C-N bond in 3-(o-aryl)-5-methyl- rhodanines using NMR spectroscopy and computational studies. Electron density topological analysis of the transition states

Doi:10.1039/b406556e
(2004)
The ozonation of silanes and germanes: An experimental and theoretical investigation

Doi:10.1021/ja058065v
(2006)
Assembly of an allenylidene ligand, a terminal alkyne, and an acetonitrile molecule: Formation of osmacyclopentapyrrole derivatives

Doi:10.1021/ja058355b
(2006)
New cytotoxic oleanane saponins from the infructescences of Polyscias amplifolia from the Madagascar rainforest

Doi:10.1055/s-2003-39711
(2003)

Article Doi