Regio- and stereoselective methoxyselenenylation of chiral 2-vinyl perhydro-1,3-benzoxazines promoted by selenium-heteroatom nonbonded interactions

DOI: 10.1021/jo052582e

Source and publish data:

Journal of Organic Chemistry p. 2424 - 2428 (2006)

Update date:2022-08-04

Topics: Chiral Stereoselective Regioselective

Authors:

Pedrosa, Rafael

Andres, Celia

Arias, Raquel

Mendiguchia, Pilar

Nieto, Javier

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Article abstract of DOI:10.1021/jo052582e

Regio- and diastereoselective methoxyselenenylations of double bonds attached to the N,O-ketalic carbon of chiral perhydrobenzoxazines occur in high yields by reaction with benzeneselenenyl chloride in dichloromethane-methanol. The diastereoselection is d

Full text of DOI:10.1021/jo052582e

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