Helvetica Chimica Acta p. 1898 - 1915 (1986)
Update date:2022-08-05
Topics:
Huber, Stefan
Stamouli, Peristera
Jenny, Titus
Neier, Reinhard
(E)- and (Z)-1,3-Butadienyl thiocyanates 3, 4, and 12-15 have been synthesized selectively.Their use as dienes for Diels-Alder reactions followed by <3,3>-sigmatropic shift to obtain an isomeric isothiocyanate has been studied.The butadienyl thiocyanates are, unfortunately, not very reactive in Diels-Alder reactions.This disadvantage can be overcome, if a trapping reaction with EtOH is added to the two-step sequence.This sequence allows to get good yields of the O-ethyl thiocarbamates 18-23, even if the first two reactions have not favorable equilibrium constants.
View MoreZhejiang Sucon Silicone Co.,Ltd
Contact:+86-575-88046692
Address:Qisheng Rd., Paojiang Industrial Zone, Shaoxing, Zhejiang, China.
Contact:+44 (0)161 367 9441
Address:
Jingzhou TianHe Sci&Tech Chemical Co., Ltd.
Contact:86-716-8331612
Address:Jiangjin Road, #18, High-grade technology industries development district, Jingzhou city, Hubei province
Contact:+86-021-58123769
Address:No.780 of Cailun Road,Zhangjiang Hi-tech Park,Pudong,Shanghai
Shanghai Pengkai Chemical Co.,Ltd
Contact:+86-21-60526671
Address:No.4226 Duzhuang Rd Minhang District Shanghai China
Doi:10.1139/v61-095
(1961)Doi:10.1007/BF00505776
(1983)Doi:10.1016/j.dyepig.2013.04.009
(2013)Doi:10.1016/0031-9422(88)80686-1
(1988)Doi:10.1016/j.jorganchem.2005.09.052
(2006)Doi:10.1016/j.tetlet.2006.01.116
(2006)
