A comparative study of the chelating ability of the -N(R)-(CH 2)n-CO-N(R)2 framework in σ-aryl palladium(II) complexes derived from 2-iodoanilines and 2-iodobenzylamines. Synthesis of new types of terdentate [C,N,O] Pd(II)

Article abstract of DOI:10.1021/om051014m

The reaction of iodo anilines 2-IC₆H₄-N(Me)-CH ₂-CO-N(R)₂ (R = Me, 1a; R = Et, 1b) with Pd ₂(dba)₃ afforded binuclear Pd(II) complexes [Pd{η-(N,C)-μ-N(Me)(C₆H₄-2)CH