REACTIONS OF A 2-PICOLYL-BRIDGED PALLADIUM(II) COMPLEX WITH SOME PYRAZOLE DERIVATIVES

Article abstract of DOI:10.1016/0022-328X(83)80141-7

A 2-picolyl-bridged dinuclear complex, <2> (I) reacted with alkali metal salts of poly(1-pyrazolyl)borates, Na(BPz4) (Pz = 1-pyrazolyl), Na(HBPz3), and K(H2BPz2) to afford the complexes, <2> (II), (III), and <2> (V), respectively.Complexes II and V retained the 2-picolyl bridge, whereas III was mononuclear without the bridge.Complex I was treated with hydrated silver perchlorate in the presence of tris(1-pyrazolyl)methane to give <2>(ClO4)2 (VI) without incorporating the neutral ligand.