Journal of the Chemical Society. Chemical communications p. 281 - 282 (1984)
Update date:2022-07-31
Topics:
Auburn, Mary J.
Stobart, Stephen R.
Addition of PPh2CH2CH2SiMe22H to a cis adduct a single co-ordination position; subsequent rearrangement whereby 2H becomes equally distributed among the two hydridic sites is intramolecular with ΔG%298 = 19.3 +/- 3.2 kcal mol-1 (1 kcal = 4.184 kJ).
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