Tetrahedron p. 2825 - 2830 (1983)
Update date:2022-07-29
Topics:
Arts, N. B. M.
Weenen, H.
Klunder, A. J. H.
Zwanenburg, B.
The synthesis of two 5-substituted homocuneyl 4-acetates viz 4-acetoxy-5-carbomethoxypentacyclo<4.3.0.02.4.03.8.05.7>nonane (8) and 4-acetoxy-5-benzoylpentacyclo<4.3.0.02.4.03.8.05.7>nonane (9) is described starting from dicarboxylic acid (10).The base induced cage opening of these acetates has been studied.It was found for 9 that the regiochemistry of this process is not affected by the carbonyl containing functionality at C5.Exclusive opening of the cyclopropanol ring is observed.
View MorePuyang Huicheng Electronic Material Co., Ltd
website:http://huichengchem.weba.testwebsite.cn/index_en.html
Contact:+86-393-8910800
Address:West Section Shengli Road, Puyang457000, China
Nanjing Fayekong Chemcial Co.,Ltd(expird)
Contact:86-25-58813444
Address:Rm 1503, Unit 1, Building 5, Zijinnanyuan, Nanjing, Jiangsu, China
Dalian RSD International Trade Co.,Ltd.(expird)
Contact:86-22-60875058 58610575
Address:Wantong International Areas, Hongqiao District, Tianjin, China.China
Nanjing Chemical Material Corp.(NCMC)
website:http://www.njchemm.com
Contact:0086-25-83172879
Address:B12 Technology and Innovation Building, Nanjing Tech University, No.5 New Model Road
Weifang Jahwa Chemical Co.,Ltd
Contact:0086-536-8897731,8897730
Address:No.5166 East Dongfeng Street,Weifang,Shandong,China
Doi:10.1021/jo00085a016
(1994)Doi:10.1002/anie.201810204
(2018)Doi:10.1021/ja00532a042
(1980)Doi:10.1039/a803769h
(1998)Doi:10.1016/S0020-1693(00)95545-2
(1979)Doi:10.1016/S0008-6215(00)85655-4
(1980)
