Tetrahedron p. 2825 - 2830 (1983)
Update date:2022-07-29
Topics:
Arts, N. B. M.
Weenen, H.
Klunder, A. J. H.
Zwanenburg, B.
The synthesis of two 5-substituted homocuneyl 4-acetates viz 4-acetoxy-5-carbomethoxypentacyclo<4.3.0.02.4.03.8.05.7>nonane (8) and 4-acetoxy-5-benzoylpentacyclo<4.3.0.02.4.03.8.05.7>nonane (9) is described starting from dicarboxylic acid (10).The base induced cage opening of these acetates has been studied.It was found for 9 that the regiochemistry of this process is not affected by the carbonyl containing functionality at C5.Exclusive opening of the cyclopropanol ring is observed.
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Doi:10.1021/jo00085a016
(1994)Doi:10.1002/anie.201810204
(2018)Doi:10.1021/ja00532a042
(1980)Doi:10.1039/a803769h
(1998)Doi:10.1016/S0020-1693(00)95545-2
(1979)Doi:10.1016/S0008-6215(00)85655-4
(1980)
