Chemistry of Natural Compounds p. 451 - 454 (1983)
Update date:2022-08-03
Topics:
Kozlov, N. G.
Kalechits, G. V.
Vyalimyae, T. K.
The reductive amination of d-fenchone by aliphatic nitriles has been studied.A probable reaction pathway is suggested, and the stereochemical composition of the products has been determined.It has been established with the aid of 13C NMR that reaction forms a mixture of isomeric optically active N-alkyl-1,2,3-trimethylbicyclo<2.2.1>hept-2-ylamines with a 3:1 ratio of endo and exo isomers.The absolute configurations of the amines synthesized have been determined.
View Moreshanghai hekang chemical co.ltd
Contact:021-54173790
Address:328 WuHe Road, Building #A, 2nd Floor, Minhang, Shanghai 201109, China
Improve Medical Technology(Nanxiong) Co., Ltd
Contact:86-751-3836997
Address:No.33, Pingan First Road, Fine Chemical Industry Base, Nanxiong City, Shaoguan, Guangdong, China
Contact:86 21 3772 9386
Address:Rm.1803,Starry Bldg.1,1505 Meijiabang Road,Shanghai 201620 China
Taizhou Chemedir Biopharm-tech Co., Ltd
Contact:+86 523 86200218
Address:G09, No. 1 Avenue China Medical City, Taizhou,Jiangsu, China
Qingdao XinYongAn Chemicals Co., Ltd
Contact:+86-532-81107967
Address:Chengyang dual-port industrial park by the sea，Qingdao
Doi:10.1021/ac00270a022
(1984)Doi:10.1248/cpb.31.2632
(1983)Doi:10.1002/anie.200504247
(2006)Doi:10.1002/ardp.200500150
(2005)Doi:10.1002/adsc.201701532
(2018)Doi:10.1039/b415691a
(2005)
