FACTORS AFFECTING STABILITY AND EQUILIBRIA OF FREE RADICALS-XII CAPTO-DATIVE DIARYLAMINYLS WITH POLYNITROPHENYL AND 3,5-di-t-BUTYLPHENYL GROUPS

Article abstract of DOI:10.1016/S0040-4020(01)90899-3

The synthesis of 3,5-di-t-butylphenyl-polynitrophenylamines is reported, with 2,6-dinitro- and 2,4,6-trinitrophenyl groups.Oxidation converts these amines into capto-dative diarylaminyls which are stable in solution at room temperature.Their ESR spectra a