Studies of Vitamin D Oxidation. 4.Regio- and Stereoselective Epoxidation of Vitamin D

DOI: 10.1021/jo00183a012

Source and publish data:

Journal of Organic Chemistry p. 1537 - 1539 (1984)

Update date:2022-08-04

Topics:

Authors:

Nakayama, Keiko

Yamada, Sachiko

Takayama, Hiroaki

Nawata, Yoshiharu

Iitaka, Yoichi

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Article abstract of DOI:10.1021/jo00183a012

Regio- and stereoselective epoxidations of vitamin D₃ at the 7,8- and 5,6-double bonds were performed.Epoxidation with m-chloroperbenzoic acid gave exclusively (7R)-7,8-epoxyvitamin D₃ (81percent) while epoxidation with tert-butyl hy

Full text of DOI:10.1021/jo00183a012

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