TOTAL SYNTHESIS OF (+/-)-AVENACIOLIDE VIA THE β-VINYLBUTENOLIDE ANNULATION

DOI: 10.1246/cl.1983.881

Source and publish data:

Chemistry Letters p. 881 - 884 (1983)

Update date:2022-07-29

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Authors:

Kido, Fusao

Tooyama, Youichi

Noda, Yoshihiro

Yoshikoshi, Akira

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Article abstract of DOI:10.1246/cl.1983.881

Annulation reaction of α-formylcaprylate (5) with 2,5-dihydro-3-phenylthio-4-vinylfuran-2-one (2), followed by dehydration, oxidation, and rearrangement, provided an epimeric mixture of 2,4,5,6-tetrahydro-6-hexyl-4-hydroxy-6-methoxycarbonylbenzofuran-2-on

Full text of DOI:10.1246/cl.1983.881

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