Tetrahedron Letters p. 5133 - 5136 (1983)
Update date:2022-08-03
Topics: Reactivity Double bond Cyclohexene Substituent Influence Remote substituents
Zefirov, Nikolai S.
Samoshin, Vyacheslav V.
Zemlyanova, T.G.
The rate of addition of chlorine to the axial conformer of 4-RO-cyclohexenes is faster than for addition to the equatorial conformer.The deactivation of the double bond by an equatorial electronegative substituent via orbital interactions is proposed to a
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