STEREOSELECTIVE REDUCTION OF α-ALKOXY ACETYLENIC KETONES WITH ZINC BOROHYDRIDE AND K-SELECTRIDE.

DOI: 10.1016/S0040-4039(00)98885-3

Source and publish data:

Tetrahedron Letters p. 5139 - 5142 (1985)

Update date:2022-08-05

Topics:

Authors:

Takashi, Takahashi

Masahiro, Miyazawa

Jiro, Tsuji

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Article abstract of DOI:10.1016/S0040-4039(00)98885-3

Reduction of α-benzyloxy acetylenic ketones with zinc borohydride afforded the erythro-acetylenic vicinal diols in 95percent stereoselectivity, while reduction with K-selectride gave the isomeric threo-diols in 90percent stereoselectivity.

Full text of DOI:10.1016/S0040-4039(00)98885-3

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