Chemistry Letters p. 61 - 64 (1985)
Update date:2022-08-03
Topics:
Uekama, Kaneto
Imai, Teruko
Hirayama, Fumitoshi
Otagiri, Masaki
Hibi, Toru
Yamasaki, Masaki
The chiral discrimination of β-cyclodextrin ((β-CyD) was demonstrated by measuring 270 MHz 1H-NMR spectra, using dl-pirprofen (PF) as a guest molecule.Upon binding to β-CyD, the induced 1H-chemical shifts of PF, particularly in the phenylpropionic acid portion, were significantly different between the d- and l-isomers, while no enantiomeric difference was observed in the abscence of β-CyD.
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