Journal of Organic Chemistry p. 4317 - 4325 (1985)
Update date:2022-08-04
Topics:
Keck, Garry E.
Kachensky, David F.
Enholm, Eric J.
Full details of the total synthesis of pseudomonic acid C from L-lyxose are described.Key features of the approach involve feee-radical allylation for stereoselective C-C bond formation at C4 of lyxose, Frater alkylation to generate correct stereochemistry at C12 and C13, and stereoselective intramolecular Michael addition to establish the correct stereochemistry of the "anomeric" appendage.
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