Synthetic Communications (2020)
Update date:2022-07-29
Topics:
Dai, Enrui
Dong, Ying
Dong, Yongrui
Kong, Rui
Liang, Deqiang
Liu, Guangzhang
Ma, Yinhai
Wu, Qiong
An amide-assisted arene nitration is presented, and both mono- and dinitration of protected anilines could be effected by using NaNO2 and NaNO3 as the mono- and bisnitrating agents, respectively. This divergent synthesis is transition-metal- and acid-free, and features a broad substrate scope, low cost, and ortho–para selectivity.
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Doi:10.1039/C8OB02899K
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