Novel Cyclopentabenzofuran Intermediates for the Synthesis of Acorane-Alaskane Sesquiterpenes: Total Synthesis of (+/-)-β-Acorenol and (+/-)-Acorenone

DOI: 10.1039/c39840000781

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 781 - 782 (1984)

Update date:2022-08-04

Topics:

Authors:

Iwata, Chuzo

Nakamura, Shizuo

Shinoo, Yasutaka

Fusaka, Takafumi

Kishimoto, Michie

et al. et al.

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Article abstract of DOI:10.1039/c39840000781

Cyclopentabenzofuran derivatives (5a) and (5b) were synthesized from spirodienone esters (6a) and (6b), respectively, and the utility of these intermediates in acorane-alaskane sesquiterpene synthesis is illustrated by their conversion into (+/-)-β-acorenol (4a) and (+/-)-acorenone (1).

Full text of DOI:10.1039/c39840000781

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