Novel Cyclopentabenzofuran Intermediates for the Synthesis of Acorane-Alaskane Sesquiterpenes: Total Synthesis of (+/-)-β-Acorenol and (+/-)-Acorenone

DOI: 10.1039/c39840000781

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 781 - 782 (1984)

Update date:2022-08-04

Topics:

Authors:

Iwata, Chuzo

Nakamura, Shizuo

Shinoo, Yasutaka

Fusaka, Takafumi

Kishimoto, Michie

et al. et al.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39840000781

Cyclopentabenzofuran derivatives (5a) and (5b) were synthesized from spirodienone esters (6a) and (6b), respectively, and the utility of these intermediates in acorane-alaskane sesquiterpene synthesis is illustrated by their conversion into (+/-)-β-acorenol (4a) and (+/-)-acorenone (1).

Full text of DOI:10.1039/c39840000781

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:2-((1S,4R)-4,8-Dimethyl-spiro[4.5]dec-1-yl)-propan-2-ol

Cas No:89949-50-8

R&D Labs maybe for 89949-50-8

Okeanos Tech.Co.,LTD

Contact:+86-10-62651721

Address:29 Yongxing Road, Daxing District,Beijing China
Shenzhen Sungening Medicine Co., Ltd

Contact:+86-871-65110906

Address:Room702, Building 2, 365 Dianchi Road, Kunming, Yunnan Province, P.R. China
Brichem ( Haikou ) Co. Ltd.

Contact:86-898-65311214

Address:Room 102, BLDG. 68 Jiangnan City, No. 66 Heping Road,Haikou, Hainan, China
Jinan Yijialian Economic and Trade Development Co., Ltd.

Contact:+86 0531-66729596

Address:jinan
Frapp's Chemical (NFTZ) Co.,Ltd

Contact:+86-576-86137892

Address:General Chamber of Commercial Building, 159 Wanchang Middle Road, Wenling, Zhejiang, China

Relevant to this article

Towards C-2 symmetrical macrocyles with an incorporated sucrose unit

Doi:10.1139/V06-035
(2006)
Pyrrolotriazine-5-carboxylate ester inhibitors of EGFR and HER2 protein tyrosine kinases and a novel one-pot synthesis of C-4 subsitituted pyrrole-2,3-dicarboxylate diesters

Doi:10.1139/V06-037
(2006)
Synthesis of new class dipeptide analogues with improved permeability and antithrombotic activity

Doi:10.1016/j.bmc.2006.03.026
(2006)
The synthesis of methylated epigallocatechin gallate

Doi:10.1007/s10600-015-1317-5
(2015)
Antivertigo agents. I. Structure-activity relationships of 2-(2-aminoethyl)pyridines

Doi:10.1248/cpb.32.553
(1984)
Synthesis, photochemical isomerization and photophysical properties of hydrazide-hydrazone derivatives

Doi:10.1039/d0nj05172a
(2021)

Article Doi