Novel Cyclopentabenzofuran Intermediates for the Synthesis of Acorane-Alaskane Sesquiterpenes: Total Synthesis of (+/-)-β-Acorenol and (+/-)-Acorenone

DOI: 10.1039/c39840000781

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 781 - 782 (1984)

Update date:2022-08-04

Topics:

Authors:

Iwata, Chuzo

Nakamura, Shizuo

Shinoo, Yasutaka

Fusaka, Takafumi

Kishimoto, Michie

et al. et al.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39840000781

Cyclopentabenzofuran derivatives (5a) and (5b) were synthesized from spirodienone esters (6a) and (6b), respectively, and the utility of these intermediates in acorane-alaskane sesquiterpene synthesis is illustrated by their conversion into (+/-)-β-acorenol (4a) and (+/-)-acorenone (1).

Full text of DOI:10.1039/c39840000781

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:2-((1S,4R)-4,8-Dimethyl-spiro[4.5]dec-1-yl)-propan-2-ol

Cas No:89949-50-8

R&D Labs maybe for 89949-50-8

Tianjin Tensing Fine Chemical Research Develop Centre

Contact:86-022-23718576,13032267585

Address:2-2-201,13 Guiyuan road,Huayuan Industry district,Tianjin,china
Shuanghe Bio-Technology Limited(expird)

Contact:+86-571-61710758,18968016640

Address:Jinqiao north road 916# Fuyang
Chinese Peptide Company

Contact:86-571-86737118-8689

Address:No.69, 12 Street, HEDA, Hangzhou, Zhejiang, China
Hefei TNJ chemical industry co.,ltd

website:https://www.tnjchem.com

Contact:+86-551-65418695

Address:B911 Xincheng Business Center, Qianshan Road, Hefei Anhui China
Sanming Coffer Fine Chemical Industrial Co., Ltd

website:http://www.cofferxm.com/

Contact:+86-598-5853979

Address:Jin-sha Yuan Chuang-ye Park,Hi-Tech Development Zone,Sanming City P.R.China

Relevant to this article

Towards C-2 symmetrical macrocyles with an incorporated sucrose unit

Doi:10.1139/V06-035
(2006)
Pyrrolotriazine-5-carboxylate ester inhibitors of EGFR and HER2 protein tyrosine kinases and a novel one-pot synthesis of C-4 subsitituted pyrrole-2,3-dicarboxylate diesters

Doi:10.1139/V06-037
(2006)
Synthesis of new class dipeptide analogues with improved permeability and antithrombotic activity

Doi:10.1016/j.bmc.2006.03.026
(2006)
The synthesis of methylated epigallocatechin gallate

Doi:10.1007/s10600-015-1317-5
(2015)
Antivertigo agents. I. Structure-activity relationships of 2-(2-aminoethyl)pyridines

Doi:10.1248/cpb.32.553
(1984)
Synthesis, photochemical isomerization and photophysical properties of hydrazide-hydrazone derivatives

Doi:10.1039/d0nj05172a
(2021)

Article Doi