Tetrahedron p. 211 - 214 (1984)
Update date:2022-07-31
Topics: Chlorination Reaction Unusual
Hashem, Md. Abul
Weyerstahl, Peter
Green, Bernard S.
The diene 1a reacted with CHCl3/aq.NaOH/PTC in CH2Cl2 unexpectedly to give a mixture of the chlorination products 2 and 3a.Usual chlorination with Cl2 yielded similarly 2, 3a, and 3b dependent on the amount of Cl2.The formation of 2 as well as the reaction of 7 to give 9 (besides 8) shows an unusual Cl-Cl-interaction.
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