Journal of Organic Chemistry p. 2152 - 2158 (1984)
Update date:2022-08-04
Topics:
Jeganathan, S.
Johnston, Allen D.
Kuenzel, Elizabeth A.
Norman, Anthony W.
Okamura, Willian H.
The lithium salt of the terminal allene 12a was reacted with keto enol ether 13 to give the vinylallenones 8a(6R) and 9a(6S).On reduction with sodium borohydride, 8a afforded vinylallenols 8b(1R,6R) and 8c(1S,6R); similarly 9a gave 9b(1R,6S) and 9c(1S,6S)
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