REACTIONS OF SUBSTITUTED CARBONYL COMPLEXES OF MOLYBDENUM(0), Mo(CO)4(DAB) and Mo(CO)2(PPh3)2(DAB) WITH Cl2, Br2 AND I2 (DAB=1,4-DIAZABUTADIENE)

DOI: 10.1016/S0022-328X(00)99183-6

Source and publish data:

Journal of Organometallic Chemistry p. 193 - 200 (1984)

Update date:2022-08-04

Topics:

Authors:

Iglesias, M.

Llorente, A.

Pino, C. Del

Santos, A.

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Article abstract of DOI:10.1016/S0022-328X(00)99183-6

The reactions of Mo(CO)4(DAB) compounds (DAB = diacetyldihydrazone (DDH), glyoxalcyclohexylamine (GCy)) with Cl2, Br2 and I2 under mild conditions can be described as oxidative elimination reactions.CO is eliminated, and seven-coordinate molybdenum(II) sp

Full text of DOI:10.1016/S0022-328X(00)99183-6

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