Synthetic applications of samarium(II) iodide mediated regioselective cleavage of phenylsulfonyl activated cyclopropyl ketones

DOI: 10.1016/S0040-4039(98)02514-3

Source and publish data:

Tetrahedron Letters p. 1019 - 1020 (1999)

Update date:2022-08-05

Topics:

Authors:

Reutrakul, Vichai

Saeeng, Rungnapha

Pohmakotr, Manat

Kongsaeree, Palangpon

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Article abstract of DOI:10.1016/S0040-4039(98)02514-3

Reductive cleavage of phenylsulfonyl activated cyclopropyl ketones with samarium(II) iodide led regioselectively to samarium enolates or dienolates. These were trapped with some alkylating agents.

Full text of DOI:10.1016/S0040-4039(98)02514-3

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