Synthetic applications of samarium(II) iodide mediated regioselective cleavage of phenylsulfonyl activated cyclopropyl ketones

DOI: 10.1016/S0040-4039(98)02514-3

Source and publish data:

Tetrahedron Letters p. 1019 - 1020 (1999)

Update date:2022-08-05

Topics:

Authors:

Reutrakul, Vichai

Saeeng, Rungnapha

Pohmakotr, Manat

Kongsaeree, Palangpon

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(98)02514-3

Reductive cleavage of phenylsulfonyl activated cyclopropyl ketones with samarium(II) iodide led regioselectively to samarium enolates or dienolates. These were trapped with some alkylating agents.

Full text of DOI:10.1016/S0040-4039(98)02514-3

Products guided by the article

Product name:(2-benzenesulfonyl-3-phenyl-cyclopropyl)-phenyl-methanone

Cas No:903900-95-8

R&D Labs maybe for 903900-95-8

Sarchem Laboratories, Inc.

Contact:732.938.2777

Address:5012 Industrial Road Farmingdale, NJ 07727
Yancheng Creator Chemical Co., Ltd

Contact:0086-515-88710008 88710068 88710858 88710868

Address:No.21 Renming Road, Longgang Town, Yandu County,Yancheng City
SHENYANG COMEBOARD TECHNOLOGY CO., LTD

Contact:+86-24-25724626

Address:Room2210,Tianbao International Building,No.8-1 Weigong South Street,Tiexi District,Shenyang,China
Shandong Yaroma Perfumery Co., Ltd.

Contact:+86- 531- 88024598

Address:7-702 Caizhi Central, 59 Gong Ye South Road, Jinan City,250101, P. R. China
Chuzhou Baiao Biologhy S&T Co., Ltd.

Contact:+86-25-83212599；+86-25-83212699 13705185959

Address:Room 905, Tianzheng International Platza, No.399, Zhongyang Road ,Nanjing, Jiangsu Province, China

Relevant to this article

Porphyrazine with bulky 2-(1-adamantyl)-5-phenylpyrrol-1-yl periphery tuning its spectral and electrochemical properties

Doi:10.1016/j.poly.2015.05.033
(2015)
Studies directed towards the synthesis of antascomicin A: stereoselective synthesis of the C22-C34 fragment of the molecule

Doi:10.1016/j.tetlet.2006.05.115
(2006)
Role of the metal oxidation state in the SNS-Cr catalyst for ethylene trimerization: Isolation of Di- and trivalent cationic intermediates

Doi:10.1021/ja0623717
(2006)
[4+2]-Cycloaddition of sterically hindered thiophene S-oxides to alkenes and SO extrusion reactions of the cycloadducts

Doi:10.1080/10426507.2015.1100191
(2016)
N-Trimethylsilyl Imines: Applications to the Synthesis of β-Lactams

Doi:10.1021/ja00329a029
(1984)
Synthesis of [3]rotaxanes that utilize the catalytic activity of a macrocyclic phenanthroline-Cu complex: Remarkable effect of the length of the axle precursor

Doi:10.1002/chem.201405090
(2015)

Article Doi