The Action of Nitrenes on Halogenothiophenes; Formation of Thiophene S,N-Ylides

DOI: 10.1039/c39840000190

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Journal of the Chemical Society. Chemical communications p. 190 - 191 (1984)

Update date:2022-08-05

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Authors:

Meth-Cohn, Otto

Vuuren, Gerda van

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Article abstract of DOI:10.1039/c39840000190

When ethyl or phenyl azidoformate, or p-tolylsulphonyl azide are decomposed in warm tetrachlorothiophene, tetrachlorothiophene S,N-ylides are formed; 2,5-dichloro-, 2,5-dibromo-, and tetrabromo-thiophene on the other hand give products arising from attack at the α-position followed by rearrangement.

Full text of DOI:10.1039/c39840000190

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