Enantioselective Syntheses of Aldols and Homoallylic Alcohols from 1,3-Dioxolan-4-ones Using Mandelic Acid as Chiral Auxiliary

DOI: 10.1021/jo00187a048

Source and publish data:

Journal of Organic Chemistry p. 2513 - 2516 (1984)

Update date:2022-08-03

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Authors:

Mashraqui, Sabir H.

Kellogg, Richard M.

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Article abstract of DOI:10.1021/jo00187a048

The 1,3-dioxolan-4-ones obtained by condensation of (S)-(+)- or (R)-(-)-mandelic acid with aldehydes and ketones react under electrophilic conditions cleanly and with reasonable diastereoselectivities with enol silyl ethers or allylsilanes.The chiral auxi

Full text of DOI:10.1021/jo00187a048

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