Base-promoted Rearrangement of Siloxyammonium Salts: a New Method of Dealkylation of Tertiary Amines via Their N-Oxides

DOI: 10.1039/c39840000192

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 192 - 193 (1984)

Update date:2022-08-03

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Authors:

Okazaki, Renji

Tokitoh, Norihiro

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Article abstract of DOI:10.1039/c39840000192

Siloxyammonium salts prepared from tertiary amine N-oxides and trialkylsilyl trifluoromethanesulphonate undergo rearrangement in the presence of strong bases to give α-siloxyamines, which can be converted into secondary amine derivatives.

Full text of DOI:10.1039/c39840000192

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