Synthesis of cyclophellitol utilizing a palladium chloride mediated-ferrier-II rearrangement

DOI: 10.3390/10080901

Source and publish data:

Molecules p. 901 - 911 (2005)

Update date:2022-08-05

Topics:

Authors:

Takahashi, Hideyo

Ikegami, Shiro

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Article abstract of DOI:10.3390/10080901

Cyclophellitol and its C3-epimer have been synthesized from 5-enoglucopyranoside and 5-enomannopyranoside, respectively. The carbocyclic skeleton was constructed through a Ferrier-II reaction meditated by PdCl ₂.

Full text of DOI:10.3390/10080901

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Product name:methyl 2-O-benzoyl-3,4-di-O-benzyl-6-deoxy-6-iodo-α-D-mannopyranoside

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