Carbohydrate Research p. 209 - 218 (1980)
Update date:2022-08-04
Topics:
Poncini, Laurence
Richards, Geoffrey N.
The kinetics of thermolysis of sucrose in solution in anhydrous dimethyl sulphoxide have been studied.The reaction appears to be facilitated by intramolecular hydrogen-bonding and is inhibited by intermolecular hydrogen-bonding to water or alcohols.The thermolysis yields α-D-glucopyranose (which then anomerises) and the fructofuranosyl carbonium ion which can react with benzyl alcohol to yield benzyl α- and β-D-fructofuranosides.This fructosyl cation is probably also the precursor for the formation of 2,6-anhydrofructofuranose in the thermolysis of sucrose.
View MoreLandz International Company Ltd.
Contact:0086-21-58891610
Address:985 Dongfang Road, Pudong, Shanghai 200122 China
Contact:86-511-85210668 0511-85210668, 85210818, 85210898
Address:Yihai Garden E-902,NO.99 Daxi RD., Zhenjiang Jiiangsu ,China
Anqing World Chemical Co., Ltd.
Contact:+86-556-5800026
Address:Daguan Economic Development Zone of circular economy industrial park Anqing City Anhui province
Taizhou volsen chemical Co., Ltd
website:http://www.volsenchem.com
Contact:+86-576-88869393
Address:Jiaojiang District, Taizhou, Zhejiang, China.
Contact:0572-2722882
Address:1201,F3,xinghuibandao,
Doi:10.1021/cs400002d
(2013)Doi:10.1016/S0040-4039(03)00930-4
(2003)Doi:10.1248/yakushi1947.96.1_44
(1976)Doi:10.1055/s-1976-23981
(1976)Doi:10.1021/jacs.8b11466
(2019)Doi:10.1016/S0008-6215(00)83565-X
(1976)
