SELECTIVE MONO-CLAISEN REARRANGEMENT OF CARBOHYDRATE GLYCALS. A CHEMICAL CONSEQUENCE OF THE VNYLOGOUS ANOMERIC EFFECT

DOI: 10.1016/S0008-6215(00)90885-1

Source and publish data:

Carbohydrate Research p. 161 - 192 (1987)

Update date:2022-09-26

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Authors:

Curran, Dennis P.

Suh, Young-Ger

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Article abstract of DOI:10.1016/S0008-6215(00)90885-1

The mono-Claisen rearrangement of carbohydrate glycals is demonstrated to be a synthetically useful and mechanistically significant reaction.Addition of per-O-acetyl glycal-tert-butyldimethylchlorosilane mixture to lithium diisopropylamide generated a bis

Full text of DOI:10.1016/S0008-6215(00)90885-1

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