2-(TRIFLUOROMETHYL)ALLYLTRIMETHYLSILANE. A USEFUL BUILDING BLOCK FOR TRIFLUOROMETHYLATED ORGANIC MOLECULES

DOI: 10.1246/cl.1984.521

Source and publish data:

Chemistry Letters p. 521 - 524 (1984)

Update date:2022-08-05

Topics:

Authors:

Yamazaki, Takashi

Ishikawa, Nobuo

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Article abstract of DOI:10.1246/cl.1984.521

2-(Trifluoromethyl)allyltrimethylsilane, a new building block for the introduction of trifluoromethyl group was prepared by the Grignard reaction of ethyl trifluoroacetate with (trimethylsilyl)methylmagnesium chloride.This allylsilane underwent the reaction with aldehydes and ketones to give the adducts in good yields.

Full text of DOI:10.1246/cl.1984.521

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