Tetrahedron Letters p. 1905 - 1908 (1984)
Update date:2022-08-02
Topics:
Tamao, Kohei
Kanatani, Ryuichiro
Kumada, Makoto
A structure and reactivity relationship has been determined on the reaction of isopropyl and n-butyl Grignard reagents and n-butyllithium with vinyl-(alkoxy)silanes and (amino)silanes.The addition to the vinyl group has been analyzed in terms of the nucleophile HOMO-vinyl group LUMO interaction.
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