A CONVENIENT SYNTHESYIS OF ( RU(η-C5H5)PPh3)(CO)Cl) AND THE CATIONS (Ru(η-C5H5)(PPh3)L(CO))+ (L=CO, PMe3, OR P(OPh)3)

DOI: 10.1039/DT9840000993

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 993 - 994 (1984)

Update date:2022-08-02

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Authors:

Davies, Stephen G.

Simpson, Stephen J.

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Article abstract of DOI:10.1039/DT9840000993

Treatment of (Ru(η-C5H5)(PPh3)Cl) with sulphur under carbon monoxide at 1-3 atm in hot toluene gives quantitative yields of (Ru(η-C5H5)(PPh3)(CO)Cl), which can be further treated in warm methanol with CO, PMe3, and P(OPh)3 to give the cations (Ru(η-C5H5)(PPh3)(CO)2)+, (Ru(η-C5H5)(PPh3)(PMe3)(CO))+, and (Ru(η-C5H5)(PPh3)(P(OPh)3(CO))+ respectively.

Full text of DOI:10.1039/DT9840000993

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