Effect of diazoalkane structure on the stereoselectivity of rhodium(II) (S)-N-(arylsulfonyl)prolinate catalyzed cyclopropanations

DOI: 10.1016/0040-4039(96)00823-4

Source and publish data:

Tetrahedron Letters p. 4133 - 4136 (1996)

Update date:2022-08-04

Topics: Stereoselectivity Experimental terms rhodium(II)

Authors:

Davies, Huw M. L.

Bruzinski, Paul R.

Fall, Michael J.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0040-4039(96)00823-4

Rhodium(II) (S)-N-(arylsulfonyl)prolinate catalyzed decomposition of diazoalkanes containing a methyl ester and either a vinyl or a phenyl group in the presence of alkenes results in highly diastereoselective and enantioselective cyclopropanations.

Full text of DOI:10.1016/0040-4039(96)00823-4

Products guided by the article

Product name:1-Methyl-2-phenyl-cyclopropan-carbonsaeure-⁽¹⁾-methylester

Cas No:91495-76-0

R&D Labs maybe for 91495-76-0

A.M FOOD CHEMICAL CO., LIMITED

Contact:86-531-87100375

Address:20Floor，Bblock，1Building，pharma-valley，Jinan，China
SHANDONG AONA CHEMICAL CO.,LTD.

Contact:86-532-85762926

Address:LIUYUAN TOWN, ZAOZHUANG CITY, SHANGDONG PROVINCE.
Angelisun(Chongqing) Pharmaceutical Co., LTD.

Contact:+86-23-68030926-816

Address:D1-7 Tech & Entrepreneurs Park, Kecheng Road, Erlang Hi-Tech Areas, Chongqing, China
Changzhou Sunlight Pharmaceutical Co., Ltd.

Contact:+86-519-83131668;83139028;83138042;83137041

Address:JiuliStreet, Benniu Town Changzhou City, Jiangsu Province
Tengzhou Runlong Fragrance Co., Ltd.

website:http://www.tzrunlong.com/

Contact:0086-15665710862

Address:No. 78, Fushan Road, Biomedical Industrial Park, Dawu Town, Tengzhou, Shandong, 277514 China

Relevant to this article

Oxazole-based peptide macrocycles: A new class of G-quadruplex binding ligands

Doi:10.1021/ja064713e
(2006)
Piano-stool iron(II) complexes as probes for the bonding of N-heterocyclic carbenes: Indications for π-acceptor ability

Doi:10.1021/om060637c
(2006)
Synthesis of the Rhodiola rosea glycoside rosavin

Doi:10.1007/s10600-006-0165-8
(2006)
Doi:10.1021/jo01013a506
(1965)
Exploration of ω-side chain addition strategies for the syntheses of isocarbacyclin and 15R-16-(m-tolyl)-17,18,19,20-tetranorisocarbacyclin

Doi:10.1039/b611339g
(2006)
Chelating C4-bound imidazolylidene complexes through oxidative addition of imidazolium salts to palladium(0)

Doi:10.1002/ejic.201100940
(2012)

Article Doi