REGIOSELECTIVE C-O BOND CLEAVAGE OF ALLYLIC PHENYL CARBONATES PROMOTED BY GROUP 8 TRANSITION METAL HYDRIDO COMPLEXES

DOI: 10.1246/cl.1984.977

Source and publish data:

Chemistry Letters p. 977 - 980 (1984)

Update date:2022-08-05

Topics:

Authors:

Hayashi, Yoshinori

Komiya, Sanshiro

Yamamoto, Takakazu

Yamamoto, Akio

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Article abstract of DOI:10.1246/cl.1984.977

Carbon-oxygen bonds in allylic phenyl carbonates are selectively cleaved by hydrido complexes of Co, Ru and Rh to give Co(OPh)L3, Ru(OPh)L2 and Rh(OPh)L3 with liberation of propylene and CO2.An intermediate complex RuH(O2COEt)L3 has been isolated in the reaction of RuH2(PPh3)4 with allyl ethyl carbonate.Reaction mechanisms are also discussed.

Full text of DOI:10.1246/cl.1984.977

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