Stereoselective Carbon-Carbon Bond Formation via Alkylation of 5-C5H5)Fe(PPh3)(CO)(COMe=CHR)> (R = Me, Prn, Ph): X-Ray Crystal Structure of (Z)-5-C5H5)Fe(PPh3)(CO)(COMe=CHMe)>

DOI: 10.1039/c39840000745

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 745 - 747 (1984)

Update date:2022-08-02

Topics:

Authors:

Baird, Gordon J.

Davies, Stephen G.

Jones, Richard H.

Prout, Keith

Warner, Peter

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Article abstract of DOI:10.1039/c39840000745

<(η⁵-C5H5)Fe(PPh3)(CO)(Methoxycarbene)>+ complexes, prepared either from terminal acetylenes or from the corresponding acyl complexes, are stereoselectively deprotonated, as evidenced by the crystal structure of (Z)-<(η⁵-C5H5)Fe(PPh3

Full text of DOI:10.1039/c39840000745

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