Angewandte
Chemie
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In summary, we have developed a highly practical and
promising method for the regio-, diastereo-, and enantiose-
lective introduction of oxygen and nitrogen groups into
simple acyclic unsaturated ketones.
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Received: April 18, 2005
Revised: August 18, 2005
Published online: October 13, 2005
Keywords: amino alcohols · asymmetric catalysis ·
.
cycloaddition · dienes · nitroso compounds
[13] The NOESY experiment was conducted with both dienes (see
Supporting Information).
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[8] CCDC-271386 (3g), -271387 (6), and -271388 (9) contain the
supplementary crystallographic data for this paper. These data
can be obtained free of charge from the Cambridge Crystallo-
Angew. Chem. Int. Ed. 2005, 44, 7082 –7085
ꢀ 2005 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim
7085