Nucleophilic Addition of Silyl Enol Ethers to Aromatic Nitro Compounds: A Facile Synthesis of α-Nitroaryl Carbonyl Compounds

DOI: 10.1021/jo00197a062

Source and publish data:

Journal of Organic Chemistry p. 4571 - 4572 (1984)

Update date:2022-08-03

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Authors:

RajanBabu, T. V.

Fukunaga, Tadamichi

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Article abstract of DOI:10.1021/jo00197a062

Silyl enol ethers and silyl ketene acetals add to aromatic nitro compounds in the presence of fluoride ion sources (e.g. tris(dimethylamino)sulfonium difluorotrimethylsiliconate (TASF)) to give, after oxidation, α-nitroaryl carbonyl compounds.

Full text of DOI:10.1021/jo00197a062

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