VERSATILE RELATIVE AND ABSOLUTE STEREOCONTROL IN STANNOUS TRIFLATE MEDIATED ALDOL-TYPE REACTIONS OF 3-(2-BENZYLOXYACETYL)THIAZOLIDINE-2-THIONE

DOI: 10.1246/cl.1984.753

Source and publish data:

Chemistry Letters p. 753 - 756 (1984)

Update date:2022-08-02

Topics:

Authors:

Mukaiyama, Teruaki

Iwasawa, Nobuharu

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Article abstract of DOI:10.1246/cl.1984.753

In the stannous triflate mediated aldol-type reactions of 3-(2-benzyloxyacetyl)thiazolidine-2-thione, stereochemical course of the reactions is dramatically altered by the addition of tetramethylethylenediamine as a ligand.High asymmetric induction is also achieved by the addition of chiral diamine derived from L-prolin.

Full text of DOI:10.1246/cl.1984.753

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