CONJUGATE ADDITION OF COPPER(I) ALDIMINES TO α,β-UNSATURATED CARBONYL COMPOUNDS - SYNTHESIS OF 1,4-DIKETONES

DOI: 10.1016/0040-4039(84)80015-5

Source and publish data:

Tetrahedron Letters p. 3091 - 3094 (1984)

Update date:2022-08-04

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Authors:

Ito, Yoshihiko

Imai, Hiroshie

Matsuura, Takaharu

Saegusa, Takeo

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Article abstract of DOI:10.1016/0040-4039(84)80015-5

This paper describes the finding that BF3 etherate effectuates the conjugate additions of copper(I) aldimines, generated in situ from lithium aldimines and Cu(I) halide, to α,β-unsaturated carbonyl compounds to produce 4-(N-alkylimino)-ketones, which give

Full text of DOI:10.1016/0040-4039(84)80015-5

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