A SYNTHESIS OF METHYL 4,6-DIDEOXY-3-C-METHYL-4-(N-METHYLACETAMIDO)-α-D-ALTROPYRANOSIDE, THE 3-EPIMER OF (METHYL N-ACETYLSIBIROSAMINIDE)

Article abstract of DOI:10.1016/0008-6215(84)85274-X

The oxirane ring of 1,6:3,4-dianhydro-β-D-talopyranose reacted at C-4 with methylamine, and the product, further processed gave a 3-deoxy-C-3-methylene derivative.Iodonium ion-induced cyclisation led to an iodooxazolidinone, and deiodination, followed by